I think all three would certainly try (why wouldn't they?), though there are definitely questions about things like Russia's ability to target locations very precisely. (Also, for all three countries, the decades-long pause in testing means we don't really know if any of them are actually nuclear powers -- it might be better to write something like 'presumed nuclear powers'. That said, the generally good performance of antiquated US tech in Ukraine is a strong sign that American military maintenance probably is up to par.)
I'm admittedly very biased, but I have full faith in the US's triad working good enough to get the job done. (and that we wouldn't target population centers with no military value in such a situation, because why would we?)