I feel like without Trump's unique appeal and candidacy, Rubio would not have won the same kind of non-college educated whites that Trump won over Obama. The coalition would look a lot different, because both Clinton and Rubio were seen as appealing to college-educated upper-class suburban whites. He probably wouldn't have won MI, WI or PA. Probably his map would've looked closer to a Romney map +4-5 points everywhere. Clear popular vote victory though.
I can see him pulling off PA with completely different demographics (probably focusing on the Philly suburbs rather than Western PA), but are you saying there's a potential for a reversal of the electoral and popular vote? As in, Clinton wins the electoral college but Rubio wins the popular vote?
I can see that happen. A GOP candidate who does fairly well with minorities but doesn't overperform with non college-educated whites can win the PV but lose the EC. But if you max out non college-educated whites you massively overperform in the EC. The electoral college basically was tailormade for a candidate like Trump. But I think Rubio would have won the PV by enough to defeat Clinton with over 300 EVs.