I know I can name all 100 Senators (Atlas, I know...), and, again, I think I could get all 50 electoral vote numbers (45+ is definite) and all 50 governors (45+ is definite, again).
oooh, capitals. I'll give that a go:
Alabama Montgomery (even though that Lynnyrd Skynnyrd song mentions Birmingham)
Alaska Juneau (even though that Michelle Shocked song mentions Anchorage)
Arizona Phoenix (been there, done that, bought a t-shirt)
Arkansas Little Rock (who doesn't remember the 1992 presidential election?)
California Sacramento (easy)
Colorado Denver (easy)
Connecticut Hartford (little harder)
Delaware hmmm.. Okay, I'll go with Dover. Pretty sure it's Dover.
Florida Tallahassee (love that name)
Georgia Atlanta, maybe?
Hawaii Honolulu
Idaho Boise
Illinois Springfield (but probably a different one than Homer's)
Indiana tough one... Fort wayne, maybe? Iowa DesMoines
Kansas Carry on my wayward son. Not sure, Lawrence maybe? Kentucky Lexington Louisiana Red Stick
Maine Augusta (I was in the Capitol City Motel in Augusta eating sardine pizza the night Diana was killed)
Maryland Anapolis (the oldest and largest slave market british north america, as I recall)
Massachusetts Boston (rhymes with Austin, sort of)
Michigan tough one... Flint? Ann Arbor? Sheboygan? Hell, I don't know this one. Minnesota Saint Paul (easy)
Mississippi Jackson
Missouri Jefferson City
Montana Helena Bonham Carter
Nebraska Lincoln (penis of the plains)
Nevada Carson City
New Hampshire Concord
New Jersey Morristown, maybe? New Mexico Santa Fe (I think that might be the oldest capital in the US)
New York Albany
North Carolina Raleigh
North Dakota Bismarck
Ohio Columbus
Oklahoma Oklahoma City
Oregon Eugene Pennsylvania Harrisburg
Rhode Island Providence (Home of Lupe's, where I saw a good many rock concerts)
South Carolina Columbia
South Dakota Pierre
Tennessee Nashville
Texas Austin (Rhymes with Boston, sort of)
Utah Salt Lake City
Vermont Montpelier
Virginia Richmond
Washington Olympia
West Virginia Charleston
Wisconsin Mad Madison
Wyoming Cheyenne (that always sounds like a stripper's name and it makes me giggle)
Let's see how I did. Oops. Missed a few. I highlighted the ones I got wrong with red. I got 44 of 50. Pretty sad, really. I think I need to study a little.