When you're in Delaware, go to Rehoboth Beach. In Maryland, go to Little Italy in Baltimore, and the Walters Art Museum.
No. The answer for Delaware is drive through it as fast as possible.
Anyway, the one thing I've heard as advice for Europeans is to be wary of American summers. We don't find extreme humidity followed by sudden torrential rainfall odd, but Europeans generally do.
As my own advice, if you're flying to Washington, stay in the Washington-Baltimore-Richmond-Hampton Roads area. Any further is too much driving for not enough benefit, and you'll be driving more than you'll be seeing anyone or anything. DC by itself is a week-long trip anyway. (Although, if you do plan to go the New York or Philadelphia areas, take the Acela train, and buy a ticket now as they get more expensive closer to the date.)