Sonny Montgomery (D-MS) went from voting with the Democrats 70% in 1992 to 30% by the time he retired.
Sonny Montgomery was always very conservative for a democrat. In fact by the 1990s his voting record was much less conservative than it was earlier in his career, when he getting ACU ratings in the 70s and 80s.
If you're talking Mississippi pols, a better example is Whitten. During the first 30 years of his career he was an uber reactionary dem in the mold of someone like Rankin or Colmer and his ADA ratings were often in single digits. By the end of his career, his ADA ratings were around 50.